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What's the Difference Between Cations and Anions?

A cation is a positively charged ion formed when an atom loses one or more electrons. An anion is a negatively charged ion formed when an atom gains electrons. Together they form the basis of ionic compounds.

Short answer

Cations are positively charged ions (lost electrons), anions are negatively charged ions (gained electrons). Cations are named with '+' suffix, anions with '-' (e.g., Na⁺, Cl⁻).

Cations vs Anions
Cation (Positive)
  • Lost electrons
  • Charge: +1, +2, +3, etc.
  • e.g., Na⁺, Ca²⁺, Al³⁺
  • Metal atoms usually
Anion (Negative)
  • Gained electrons
  • Charge: −1, −2, −3, etc.
  • e.g., Cl⁻, O²⁻, PO₄³⁻
  • Non-metal atoms usually
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Step-by-step worked examples

Sodium (Na) has 11 protons and 12 electrons. Is it a cation or anion? Write its formula.

11 protons (atomic number)
12 electrons given
12 > 11 → gained 1 electron
Gained electrons → anion
Formula: Na⁻

Chlorine (Cl, 17 protons) gains 1 electron. Name the resulting ion.

17 protons + 1 electron gained = 18 electrons
18 > 17 → gained electrons
Result: Cl⁻ (chloride anion, charge −1)

Magnesium (Mg, 12 protons) loses 2 electrons. What ion forms?

12 protons, loses 2 electrons
12 protons, 10 electrons remain
10 < 12 → lost electrons
Result: Mg²⁺ (magnesium cation, charge +2)
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Flashcards

03

Quick quiz

Q1.Which type of ion has more protons than electrons?

Correct answer: B. Cations have more protons (lost electrons); anions have more electrons.

Q2.Which forms a cation: a metal or non-metal?

Correct answer: B. Metals typically lose electrons to form cations (e.g., Na⁺, Ca²⁺).

Q3.If S gains 2 electrons (35 protons), what is the charge?

Correct answer: B. Gaining 2 electrons = −2 charge. Ion is S²⁻ (sulfide anion).

Q4.What is the charge on Al³⁺?

Correct answer: C. Al³⁺ lost 3 electrons, giving it a +3 charge.
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04

Common mistakes

Cations are formed by gaining electrons.Correct: Cations are formed by losing electrons (positive charge).

Non-metals form cations.Correct: Non-metals usually gain electrons to form anions.

A cation has more electrons than protons.Correct: A cation has fewer electrons than protons (lost electrons).

All anions have charge −1.Correct: Anions can have charge −1, −2, −3, etc., depending on electrons gained.

05

FAQ

Why do metals form cations?

Metals have few valence electrons and lose them easily to achieve a stable (full outer shell) configuration.

Why do non-metals form anions?

Non-metals have many valence electrons and gain a few more to fill their outer shell completely.

Can the same element form both cations and anions?

Rarely. Hydrogen can form both H⁺ and H⁻. Most elements form only cations or anions.

What is the most common cation charge?

Metals commonly form +1 (like Na⁺, K⁺) or +2 (like Mg²⁺, Ca²⁺) cations.

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