🎓 Prepared by students from Boğaziçi University

What are Acids, Bases, and Buffer Solutions?

Acids and bases are opposite chemical species that define solution acidity. Buffers are special mixtures—weak acids plus their conjugate bases, or weak bases plus conjugate acids—that resist sudden pH changes.

Short answer

Acids donate protons (H⁺) and have pH < 7; bases accept protons and have pH > 7. Buffers contain a weak acid–conjugate base pair (or weak base–conjugate acid pair) and resist pH shifts when small amounts of acid or base are added.

Acids vs Bases vs Buffers
Acids
  • pH < 7
  • Sour taste
  • Turn litmus red
  • Donate H⁺
Bases
  • pH > 7
  • Bitter taste
  • Turn litmus blue
  • Accept H⁺
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Step-by-step worked examples

Hydrochloric acid (HCl) is a strong acid. If 0.01 M HCl solution is prepared, what is its approximate pH?

[H⁺] = 0.01 M = 10⁻² M
pH = -log[H⁺] = -log(10⁻²) = 2
Solution is strongly acidic

A buffer is made with 0.1 M acetic acid (CH₃COOH) and 0.1 M sodium acetate (NaCH₃COO). A small amount of HCl is added. Does pH change drastically?

The acetate ion (CH₃COO⁻) from the salt neutralizes added H⁺
CH₃COO⁻ + H⁺ → CH₃COOH
pH drops only slightly, not drastically
Buffer resists pH change

Sodium hydroxide (NaOH) is a strong base with concentration 0.001 M. Find [OH⁻] and pOH.

[OH⁻] = 0.001 M = 10⁻³ M
pOH = -log[OH⁻] = -log(10⁻³) = 3
At 25°C: pH = 14 − 3 = 11
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Flashcards

03

Quick quiz

Q1.Which compound is an acid?

Correct answer: B. HCl is hydrochloric acid—it donates H⁺ ions. NaOH is a base, NH₃ is a weak base, NaCl is a salt.

Q2.A buffer contains 0.1 M weak acid and 0.1 M its conjugate base. What happens if acid is added?

Correct answer: B. The conjugate base reacts with added H⁺, limiting pH change. A well-designed buffer minimizes the change.

Q3.Which is true about strong acids?

Correct answer: B. Strong acids fully dissociate. Weak acids partially ionize and are buffered by their conjugate bases.

Q4.A buffer system requires…

Correct answer: B. A classic buffer: weak acid + its conjugate base (or weak base + conjugate acid).
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04

Common mistakes

All acids smell sharp, all bases smell nothing.Correct: Some acids (like acetic) have odors; some bases (like ammonia) are pungent. Never smell chemicals.

A buffer means the pH never changes.Correct: A buffer resists large changes, but the pH still shifts slightly when acid or base is added.

Strong acids are better buffers.Correct: Buffers work best with weak acids or bases because they partially ionize.

Water is neutral, so it cannot become acidic.Correct: Water is neutral only when pure; adding acid or base changes its pH immediately.

05

FAQ

What is the difference between acids and bases?

Acids donate protons (H⁺) and have pH < 7; bases accept protons and have pH > 7. At pH = 7 (neutral), [H⁺] = [OH⁻].

What is a buffer solution used for?

Buffers keep pH stable in chemistry, biology (blood), and pharmaceuticals by resisting acid–base additions.

Can a buffer work forever?

No—buffers have a capacity limit. Once all the weak acid or base is consumed, the buffer fails and pH changes rapidly.

What are everyday examples of buffers?

Blood (buffered by H₂CO₃/HCO₃⁻), soil, and milk all contain buffering systems.

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