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What is Molarity (Concentration)?

Molarity is the most common way chemists express concentration — how much solute is dissolved in a given volume of solution. It links the amount of substance (moles) directly to the space it occupies in solution.

Short answer

Molarity is calculated as M = n/V, where n is the moles of solute and V is the volume of solution in liters; its unit is mol/L, also written as M.

Molarity vs Volume (at fixed 2 mol solute)
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x: Volume (L) · y: Molarity (mol/L)
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Try it: interactive calculator

Molarity M
2mol/L
= 2/1
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Step-by-step worked examples

0.5 mol of NaCl is dissolved to make 2 L of solution. Find the molarity.

M = n/V
M = 0.5/2
M = 0.25 mol/L

How many moles of solute are needed to make 3 L of a 1.5 M solution?

M = n/V → n = M × V
n = 1.5 × 3
n = 4.5 mol

2 mol of HCl is dissolved in enough water to give a concentration of 4 M. Find the volume of solution.

M = n/V → V = n/M
V = 2/4
V = 0.5 L
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Flashcards

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Quick quiz

Q1.What is the molarity of a solution with 3 mol of solute in 6 L?

Correct answer: A. M = n/V = 3/6 = 0.5 mol/L.

Q2.A solution's molarity increases when…

Correct answer: C. Adding more solute to the same volume raises n/V, increasing molarity.

Q3.How many moles are in 2 L of a 3 M solution?

Correct answer: B. n = M × V = 3 × 2 = 6 mol.

Q4.What happens to molarity when you dilute a solution with water?

Correct answer: B. Dilution increases volume without adding solute, so M = n/V decreases.
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Common mistakes

Using volume of solvent instead of total volume of solution.Correct: V in M = n/V is the total volume of the solution, not just the solvent added.

Forgetting to convert grams of solute into moles first.Correct: Divide mass by molar mass to get n before applying M = n/V.

Confusing molarity (mol/L) with molality (mol/kg).Correct: Molarity uses volume of solution; molality uses mass of solvent — they're different quantities.

Assuming mixing two solutions doubles the molarity.Correct: Mixing dilutes both solutions — use conservation of moles (M₁V₁ + M₂V₂ = M_final × V_total) instead.

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FAQ

What is molarity?

Molarity is a measure of concentration equal to the moles of solute dissolved per liter of solution, written M = n/V.

What is the molarity formula?

M = n/V, where M is molarity (mol/L), n is moles of solute, and V is the volume of solution in liters.

What are examples of molarity?

Dissolving 1 mole of NaCl in 1 liter of water gives a 1 M solution; diluting it to 2 liters gives a 0.5 M solution.

How do you calculate molarity?

Divide the moles of solute by the volume of the solution in liters: M = n/V.

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