🎓 Prepared by students from Boğaziçi University

What is Environmental Chemistry?

Environmental chemistry studies the chemical processes in air, water and soil, and how pollutants harm ecosystems. It bridges chemistry, biology and geology to understand climate change, water quality and air pollution.

Short answer

Environmental chemistry applies chemical knowledge to environmental problems: analyzing pollutants, understanding transformation reactions, and designing cleanup methods for a sustainable world.

Pollutant Cycle in the Environment
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  1. 1.EmissionIndustrial, vehicle and natural sources release pollutants
  2. 2.TransportWind and water currents carry pollutants globally
  3. 3.TransformationUV light, heat and reactions change pollutant chemistry
  4. 4.AccumulationPollutants settle in soil, water or organisms (bioaccumulation)
  5. 5.DepositionPollutants settle out or enter food chains
  6. 6.RemediationNatural processes and human action attempt cleanup
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Step-by-step worked examples

A factory emits 100 kg SO₂ daily. How much H₂SO₄ acid rain can form if all SO₂ is oxidized and dissolves in water? (Molar mass SO₂ = 64, H₂SO₄ = 98 g/mol)

Moles of SO₂ = 100,000 g / 64 g/mol = 1,562.5 mol
2 SO₂ + O₂ → 2 SO₃; SO₃ + H₂O → H₂SO₄
From stoichiometry: 1 mol SO₂ → 1 mol H₂SO₄
Moles of H₂SO₄ = 1,562.5 mol
Mass of H₂SO₄ = 1,562.5 × 98 = 153,125 g ≈ 153 kg

A 50 mL water sample contains 0.5 mg Pb²⁺ ions. Calculate the concentration in ppm (parts per million). (Assume water density = 1 g/mL)

Mass of water = 50 mL × 1 g/mL = 50 g
ppm = (mass of pollutant / mass of water) × 10⁶
ppm = (0.5 mg / 50,000 mg) × 10⁶ = 10 ppm

An aquifer has 200 ppm NO₃⁻ contamination. How many kg of NO₃⁻ are in 1 million liters of water?

200 ppm = 200 mg pollutant per 1000 g water
1 million liters = 10⁹ g water
Mass of NO₃⁻ = (200 mg / 1000 g) × 10⁹ g = 200 × 10⁶ mg = 200 kg
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Flashcards

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Quick quiz

Q1.Which gas is the leading contributor to acid rain?

Correct answer: B. SO₂ from fossil fuel combustion oxidizes to SO₃, then forms H₂SO₄ in clouds.

Q2.Bioaccumulation is a process where…

Correct answer: B. Persistent toxins are not broken down and accumulate in body tissues, especially in predators.

Q3.What does ppm mean in water quality?

Correct answer: B. ppm = mg of solute per kg of solution, a common unit for low pollutant concentrations.

Q4.Which refrigerant damaged the ozone layer?

Correct answer: B. Chlorofluorocarbons (CFCs) release Cl radicals that catalyze ozone destruction in the stratosphere.
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Common mistakes

Confusing ppm with percent (%) concentrations.Correct: ppm is mg/L for dilute solutions; % is typically g/100 mL for stronger solutions.

Assuming pollutants are destroyed instantly once in the environment.Correct: Many persist for years, accumulate in organisms and cycles through the biosphere.

Forgetting that reactions in the atmosphere transform pollutants into different compounds.Correct: SO₂ oxidizes to SO₃, NO oxidizes to NO₂, and both dissolve to form acids.

Thinking ozone in the troposphere is beneficial like stratospheric ozone.Correct: Ground-level ozone (from NOₓ + VOC reactions) is a harmful air pollutant.

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FAQ

What are the main sources of air pollution?

Industry, vehicles, power plants and agricultural activities emit SO₂, NO_x, particulates and volatile organic compounds.

How does acid rain form?

SO₂ and NO_x gases oxidize in the atmosphere to form H₂SO₄ and HNO₃, falling as acidic rain.

What is water hardness and why does it matter?

Hardness is Ca²⁺ and Mg²⁺ ion concentration. High hardness reduces soap effectiveness and clogs pipes.

What is the greenhouse effect?

CO₂, CH₄ and other gases trap heat in the atmosphere, warming the Earth and changing climate.

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