🎓 Prepared by students from Boğaziçi University

What is Covalent Bonding?

Covalent bonding is when two atoms share one or more pairs of electrons to achieve stable, filled outer shells. It's the primary bonding in molecules and is very common in organic compounds, water, and gases.

Short answer

In covalent bonding, atoms share electrons rather than transfer them. A single bond shares 1 electron pair (1 line), double bonds share 2 pairs (2 lines), and triple bonds share 3 pairs (3 lines).

Ionic Bonding vs Covalent Bonding
Ionic Bonding
  • Electron transfer
  • Cation + anion
  • Electrostatic attraction
  • e.g., NaCl, MgO
Covalent Bonding
  • Electron sharing
  • Two atoms
  • Shared electron pair
  • e.g., H₂, H₂O, O₂
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Step-by-step worked examples

Hydrogen (H) forms H₂ by sharing electrons. How many electron pairs are shared?

Hydrogen: 1 proton, 1 electron (needs 2 electrons for stability)
Two H atoms approach each other
Each contributes 1 electron to a shared pair
Shared pair: 1 electron pair (single bond H—H)

In water (H₂O), oxygen bonds with two hydrogens. How many single bonds?

Oxygen: 8 protons, 6 valence electrons (needs 2 more)
Hydrogen: 1 proton, 1 valence electron (needs 1 more each)
O shares 1 electron pair with each H
Total: 2 single bonds (H—O—H)

In carbon dioxide (CO₂), carbon shares electrons with two oxygens. What type of bonds?

Carbon: 6 protons, 4 valence electrons (needs 4 more)
Oxygen: 8 protons, 6 valence electrons (needs 2 more each)
Each C=O shares 2 electron pairs
Total: 2 double bonds (O=C=O)
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Flashcards

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Quick quiz

Q1.In covalent bonding, electrons are ___.

Correct answer: B. Covalent bonding involves sharing of electrons, not transfer.

Q2.How many electron pairs does a single bond contain?

Correct answer: B. A single bond (—) is 1 shared electron pair.

Q3.In O=C=O (carbon dioxide), how many double bonds are there?

Correct answer: B. CO₂ has 2 double bonds: one between C and each O.

Q4.Which molecule has only single bonds: H₂O, O₂, or N₂?

Correct answer: C. H₂O has two O—H single bonds. O₂ and N₂ have double and triple bonds respectively.
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Common mistakes

Covalent bonding is the same as ionic bonding.Correct: Covalent bonding shares electrons; ionic bonding transfers electrons.

Only metals can form covalent bonds.Correct: Non-metals typically form covalent bonds with each other.

A double bond is always stronger than a single bond.Correct: Double bonds are stronger (2 pairs vs 1), but a triple bond is even stronger.

Covalent compounds are always molecular.Correct: Most are molecular, but some (like diamonds) are network covalent solids.

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FAQ

Why do atoms form covalent bonds?

Atoms share electrons to achieve stable, filled outer electron shells (octet rule for most non-metals).

What is the difference between a single, double, and triple bond?

Single bond = 1 shared pair, double bond = 2 shared pairs, triple bond = 3 shared pairs. Triple bonds are strongest.

Can an atom form more than one covalent bond?

Yes — most atoms form multiple bonds (e.g., carbon typically forms 4 covalent bonds).

What are examples of covalent molecules?

H₂, H₂O, CO₂, NH₃, O₂, N₂, and most organic molecules.

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